无模板剂法合成过渡金属修饰的ZSM-5及催化氧化苯甲醇

来源 :中国化学会第30届学术年会 | 被引量 : 0次 | 上传用户:zy34970348
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  不使用有机模板剂,在pH为1的水溶液中,用硝酸锰、硝酸铜、硫酸氧钒、硫酸钛等过渡金属盐和正硅酸四乙酯(TEOS)进行酸性共水解、碱性陈化24h和180℃水热晶化72 h,制得一系列过渡金属修饰的高结晶度的ZSM-5沸石(M-ZSM-5)。
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