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Although formamidinium lead iodide(FAPbI3)perovskite has shown great promise in the field of perovskite-based optoelectronic devices,it suffers the complications of a structural phase transition from a black perovskite phase(α-FAPbI3)to a yellow non-perovskite phase(α-FAPbI3).Generally,it is pivotal to avoid α-FAPbI3 since only α-FAPbI3 is desirable for photoelectric conversion and near-infrared(NIR)emission.