Copper-Catalyzed Hydrophosphorylative Ring Opening of Propargyl Epoxides:Highly Selective Access to

来源 :第十九届全国金属有机化学学术讨论会 | 被引量 : 0次 | 上传用户:huaweibo
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2,3-Allenols are highly desired building blocks in advanced organic synthesis.The transition metal catalyzed ring openings(SN2′-type) of propargyl epoxides with organometallic reagents such as Grignard,organolithium,organozinc and organoboron reagents represent one useful and reliable protocol(Scheme 1i,type a).
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