Synthesis and electrocatalytic property of two sandwich-typepolytungstocobaltate(-zincate)modified b

来源 :中国化学会第八届全国配位化学会议 | 被引量 : 0次 | 上传用户:songshuguiyu00
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  Two new sandwich-typepolyoxometalatesmodified by open-chain carboxyethyltin groups andtransitionmetals,namely[CN3H6]10[(Sn(CH2CH2COO))2MW(MW9O34)2]·6H2O(M = Co(1),Zn(2)),were synthesized in aqueous solutions by routine synthetic method.
其他文献
多金属氧酸盐作为阴离子金属氧簇具有很多重要的性质,使其在催化、药物、光、电、磁等领域具有潜在的应用价值[1,2].Evans-Showell-type型多酸在制备新型结构中是一种灵活的建筑单元,并且在催化领域有广泛的用途.
含有从轻到重稀土元素的一系列镧系配位聚合物,即{[Eu2(pydc)3(H2O)]·2H2O}n(1-Eu,H2pydc=吡啶-2,3-二羧酸),[Ln(pyc)2(Hpyc)(NO3)]n(Ln=Nd(2-Nd),Sm(3-Sm),Eu(4-Eu),Gd(5-Gd),Tb(6-Tb),Ho(7-Ho),和Er(8-Er),Hpyc =吡啶-3-羧酸)在水/溶剂热条件下合成并充分表征。
Of various luminescent transition metal complexes,those with d8 and d10 metal ions are particularly interesting because additional d8-d8/d8-d10/d10-d10 intermetallic contacts with the energy comparabl
高效节能气体分离技术的发展是应对大宗化学品绿色制造、清洁能源存储和气候变化等全球挑战的关键。吸附分离是一种节能高效的分离技术,但气体吸附分离过程普遍存在选择性和容量难以兼具的现象(trade-off 效应),导致过程能耗居高不下。
在生物系统中的各种微量金属离子中,Fe3+是有氧运输机制的关键环节,在许多酶的电子转移和氧化反应中扮演着一个重要的角色[1],过量的Fe3+会诱发心力衰竭、贫血、肝肾损伤和糖尿病等疾病[1],因此,对生物体内Fe3+水平的监测是十分必要的。
Copper-ceria as one of the very active catalysts for oxidation reactions has been widely investigated in heterogeneous catalysis.
基于第一性原理的电子结构理论计算在材料研究中发挥着日益重要的作用,不仅用于解释和分析实验现象,也日益广泛地应用于新材料的理性设计。
Coordination polymer and metal-organic framework have attracted much research interest,owing to their multifunctional properties such as magnetism,luminescence,gas storage,catalysis,chirality,and sens
Spin-crossover(SCO)complexes were one of the most attractive switchable molecular materials with the potential applications in data storage,molecular switches and sensors.
Chirality is an important category in chemical and biological systems.Chiral coordination polymers play important roles in the fields of asymmetric catalysis,chiral separation,secondharmonic generatio