【摘 要】
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Palladium has been the focus of recent research into Pt-alternative catalysts for the oxygen reduction reaction (ORR).In this manuscript,we developed a Pd catalyst supported on exfoliated montmorillon
【机 构】
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School of Chemistry and Chemical Engineering,Chongqing University,Chongqing,400044 China
【出 处】
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第十五届全国氢能会议暨第7届两岸三地氢能研讨会
论文部分内容阅读
Palladium has been the focus of recent research into Pt-alternative catalysts for the oxygen reduction reaction (ORR).In this manuscript,we developed a Pd catalyst supported on exfoliated montmorillonite (ex-MMT) nanoplatelets for the ORR.We unexpectedly found that a thin PdOx layer with a Pd-O-MMT junction is formed at the particle/support interface.The thin PdOx layer was experimentally observed.First-principle calculations further revealed that the junction is formed between the Pd atoms and the O atoms in the AlO6 octahedra of the ex-MMT.
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