In 2016,Wang and co-authors reported the catalytic α-fluoroallenoate synthesis via N-heterocyclic carbene-catalyzed fluorination reaction of alkynals[1].
First-principles quantum mechanical/molecular mechanical(QM/MM)-free energy calculations1-4 have been performed to uncover how uricase catalyzes metabolic r
A number of transition-metal complexes have been found to be efficient catalysts for kinds of hydroboration.[1] This short paper presents a DFT study to mec