【摘 要】
:
光催化反应是降解有机污染物的一种环保有效的方法.对于单一催化剂存在的可见光利用率低,光腐蚀严重的缺点,制备复合型的催化材料成为当前研究领域的当务之急.本文通过一步溶剂热反应制备出了三元草莓状Cu2O/Cu/TiO2 复合材料(形貌如图所示),利用XRD、SEM、TEM、DRS、FTIR 等技术对其进行了表征,研究了其生成机理.
【机 构】
:
河南师范大学化学化工学院 新乡 453007 河南师范大学环境学院 新乡 453007
论文部分内容阅读
光催化反应是降解有机污染物的一种环保有效的方法.对于单一催化剂存在的可见光利用率低,光腐蚀严重的缺点,制备复合型的催化材料成为当前研究领域的当务之急.本文通过一步溶剂热反应制备出了三元草莓状Cu2O/Cu/TiO2 复合材料(形貌如图所示),利用XRD、SEM、TEM、DRS、FTIR 等技术对其进行了表征,研究了其生成机理.
其他文献
Polyolefinic materials,the most used synthetic polymers,play a direct role in everyday life,since they are used in the manufacture of numerous products,such as toys,shopping bags,food packages,shampoo
The study on alkyne hydrothiolations for the construction of small molecules was reported half a century ago.1 While,this reaction was almost forgotten until Bowman and co-workers developed highly cro
Single-site early transition metal catalysts have been extensively investigated for the polymerization of nonpolar olefins.1 In the past 30 years,tremendous progress using these catalysts has led to t
Carbonyl sulfide (COS) is one of common C1 compounds (CO2,COS and CS2) with asymmetric heterocumulene structure.The coupling of these C1 building blocks with epoxides to afford polymers is an attracti
In recent publication [1]we have reported that α-methylstyrene is polymerization and nitration with nitric acid by one-pot method,polymer with high degree of nitration was obtained.But the steric stru
Reversible Complexation Mediated Polymerization (RCMP) is a new kind of living radical polymerization (LRP),which reversibly generate the corresponding alkyl radical (R·) through the reaction of an al
Competing molecular interactions in biological systems and synthetic materials can result in self-ordered hierarchical structure formation1.Thus,block polymers with incompatible segments can be formed
半导体量子点(如CdSe、CdTe 和PbTe 等)由于其独特的光学和生物化学性质而受到人们的很大关注[1,2].但是半导体量子点由于常使用镉等重金属离子将导致细胞毒性及环境污染[3].碳是人们公认的无毒的元素.碳纳米材料,如碳纳米管、富勒烯、石墨烯、纳米纤维等在纳米技术、生物传感和药物传递等方面具有重要的作用[4,5].
为了防止食品变质腐烂,在食品加工过程中添加防腐剂,常用的防腐剂有苯甲酸钠、山梨酸钾、对羟基苯甲酸脂钠等.防腐剂的过量使用会影响人类的健康,比如苯甲酸钠会影响肝脏酶对脂肪酸的作用.
近年来,可见光光催化剂在环境污染治理上具有广阔的应用前景,受到了人们的广泛关注.由于在铋盐中,Bi 的6s 和O 的2p 轨道在反键作用状态下引起价带位置升高使铋盐光催化剂通常具有窄的禁带宽度,电子和空穴更容易迁移,从而使铋系光催化剂具有良好的可见光催化活性,引起人们的极大兴趣.