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5. Solution and Suspension Polymerization of 1,3-Butadiene with CoCl2(PRPh2)2EASC Catalytic Systems

Solution and Suspension Polymerization of 1,3-Butadiene with CoCl2(PRPh2)2EASC Catalytic Systems

来源 :Asian Polyolefin Workshop (APO2013)2013亚洲聚烯烃研讨会 | 被引量 : 0次 | 上传用户：uuuiiiuuui

【摘 要】

：

A series of phosphine-cobalt(Ⅱ) dichloride complexes,[1] CoCl2(PRPh2)2 (R =Ph, Cy, n-Pr, Et, Me, H), has been used for the highly active and stereospecific pol

【作 者】

：

Qinzhuo Zhou Bo-Geng Li Suyun Jie 

【机 构】

：

StateKeyLaboratoryofChemicalEngineering,DepartmentofChemicalandBiologicalEngineering,ZhejiangUnivers

【出 处】

：

Asian Polyolefin Workshop (APO2013)2013亚洲聚烯烃研讨会

【发表日期】

：

2013年10期

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A series of phosphine-cobalt(Ⅱ) dichloride complexes,[1] CoCl2(PRPh2)2 (R =Ph, Cy, n-Pr, Et, Me, H), has been used for the highly active and stereospecific polymerization of 1,3-butadiene to produce PBDs with high cis-1,4 content on treatment with ethylaluminum sesquichloride (EASC).

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