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The novel complex {[Ag(PPh3)(μ-dpe)]1.5(BF4)}n(1)(dpe = 1,2-di(4-pyridyl)ethylene,PPh3 = triphenylphoshuine)have been synthesized and characterized by IR,singl-crystal X-ray diffraction,fluorescence spectrum and 1H and 31P NMR spectroscopy.The structure of 1 exhibits a(93,33)topological networks which has not been reported for silver complex.