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A novel 2D coordination polymer,{[Eu(H2TPIDC)(H2O)3]·2H2O}n (1),has been prepared by using the 2-(4-(1H-tetrazol-5-yl)phenyl)-1H-imidazole-4,5-dicarboxylic acid (H4TPIDC) ligand and Eu(Ⅲ) ion under hydrothermal condition.