Highly β-Stereoselective Mannosylation via Remote Acyl Group Participation

来源 :第二届糖合成化学青年学术研讨会 | 被引量 : 0次 | 上传用户：zhghliu

【摘要】

：

　　Stereoselective β-mannosylation has been recognized as one of the greatest challenges in carbohydrate chemistry.Herein,we described a new method for stereo

【作者】

：

YonghaiChai[1]LongChen[2]

【机构】

：

School of Chemistry and Chemical Engineering,Shaanxi Normal University

【出处】

：

第二届糖合成化学青年学术研讨会

【发表日期】

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2017年期

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　　Stereoselective β-mannosylation has been recognized as one of the greatest challenges in carbohydrate chemistry.Herein,we described a new method for stereoselective construction of β-mannosides by using a novel mannoside [2.2.2] lactone donor via C4 remote acyl group participation as well as the assistance of C4 substituent's steric effect.

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Highly β-Stereoselective Mannosylation via Remote Acyl Group Participation

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