We herein report a conformationally adaptive macrocycle--Zorb[4]arene,which exists in multiple conformations in the uncomplexed state.The binding cavity of zorb
Unreactive C-H bond activation is a new horizon for Frustrated Lewis Pairs(FLPs) chemistry.1 This study performed systemic DFT calculation on the mechanism of F
Hypervalent iodine reagents such as(diacyloxyiodo)arenes have been widely used in organic synthesis as stable,efficient,and environmentally benign oxidizing rea
Direct radical additions to terminal alkynes have been widely employed in organic synthesis,providing a credible access to the anti-Markovnikov products.Because
Considering that stoichiometric borane and oxidant have to be required in classical alkene anti-Markovnikov hydration process,it still remains appealing to achi
Hydrogen bonded arylamide oligomeric foldamers represent a large family of artificial secondary structures that exhibit many interesting functions in molecular
Owning to their large volume,variety structures and tunable functionality,metal-organic frameworks(MOFs) are considered as promising materials for CO2 capture[1
This research is aiming at study the mechanism and its applications of pH-dependent photo-induced release reaction of selected photosensitive aromatic carbonyl
A combined DFT and experimental study was performed to reveal the mechanism of isocyanide-alkyne cycloaddition.Our results indicate that the mechanism of th