Synthesis and Structure of a Heterobinuclear Ni(Ⅱ)-Cd(Ⅱ) Complex bridged by 2,5-Pyridinedicarboxylat

来源 :第十届国际华人无机化学研讨会 | 被引量 : 0次 | 上传用户：liuzixing0210

【摘要】

：

【作者】

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Ting-Ting Zhang Li-Qin Li He Zhang Feng-Mei Nie

【机构】

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Department of Chemistry,Capital Normal University,Beijing,100048

【出处】

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第十届国际华人无机化学研讨会

【发表日期】

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2014年4期

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Many functionally diverse metalloproteins share the unsymmetrical dimetal(Ⅱ) active site structural motif.In order to model the active structure of this kind of motif, a novel heterobinuclear Ni(Ⅱ)-Cd(Ⅱ) complex with tripodal tris(2-benzimidazolylmethyl)amine (ntb) as terminal ligand, [NiCd(ntb)2(μ-2,5-pda)](ClO4)2·7CH3OH is prepared and structurally characterized.

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Synthesis and Structure of a Heterobinuclear Ni(Ⅱ)-Cd(Ⅱ) Complex bridged by 2,5-Pyridinedicarboxylat

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