超分子有机框架分子有序簇集衍生的功能与应用

来源 :第十二届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户:shaoshao137
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2013年以来,我们基于有机小分子自组装策略,利用疏水作用为驱动力,通过葫芦脲对芳香基团二聚体的包结作用,首次在水中实现了均相周期性纳米孔阵列超分子有机框架(Supramolecular Organic Framework,SOF)的构建[1,2].作为一类正离子型可溶性有序分子簇集体,SOF具有疏水空腔,对负离子型客体和疏水性有机分子具有极强的吸收作用[3],并由此衍生新的功能.
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