【摘 要】
：
理论上电解水是生产氢气的有效策略,然而不管析氢半反应还是析氧半反应,电催化性能往往受限于贵金属的纳米材料,因此发展一种高效、稳定的非贵金属电催化剂成为了人们研
【机 构】
：
苏州大学材料与化学化工学部,苏州市,215123
论文部分内容阅读
理论上电解水是生产氢气的有效策略,然而不管析氢半反应还是析氧半反应,电催化性能往往受限于贵金属的纳米材料,因此发展一种高效、稳定的非贵金属电催化剂成为了人们研究的热点[1][2].近来,我们选择结构丰富,多孔的金属有机框架(MOF)材料作为研究对象,利用溶剂热反应通过调节反应物比例,溶剂等反应条件合成了一系列镍基的双金属有机框架的微纳材料,如海藻状和空心球状形貌的Ni/Zn-MOF材料(Fig.1),而空心球状形貌的合成方法也适用于含其他金属(Mn,Co,Cu,Pb,Cd,Ag等)的MOFs.
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