Molecular aspects of Br(o)nsted acid-catalyzed fructose conversions

来源 :2016年理论与高性能计算化学国际会议(International Conference on Theoretical | 被引量 : 0次 | 上传用户:t739155593
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  In the valorization of carbohydrate biomass,one of the main challenges is the efficient conversion of glucose to platform chemicals such as 5-hydroxymethylfurfural(HMF),which is generally realized by two consecutive reactions [1]: Reaction 1 is the isomerization of glucose to fructose,and Reaction 2 is the transformation of fructose to HMF.Although the catalysis of Reaction 2 by Br(o)nsted acids is efficient,detailed insight into the catalytic mechanisms is lacking.
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