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[Zn(L)2(H2O)](1)with 6-hydroxyloxoisoaporphine(H–L)were synthesized and characterized.Complex 1 is five-coordinated distorted tetragonal pyramid.Complex 1 exhibited selective cytotoxicity against BEL-7404,MGC80-3,Hep-G2 and T-24 cells with IC50 values in range of 8.19–11.14 μM,but low cytotoxicity to HL-7702 cells.