FACILE APPROACH FOR THE CONTROLLABLE SYNTHESIS OF STEREOREGULAR POLYESTER FROM ORGANOCATALYTIC EPOXI

来源 :The 6th International Symposium on Polymer Chemistry(2014年第六 | 被引量 : 0次 | 上传用户：xiaoyaozhu

【摘要】

：

In present work,we report a facile access to prepare stereopolyester with tunable geometric structure through the organocatalytic copolymerization of cyclohexen

【作者】

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Bin Han Binyuan Liu Xiaofang Dong Li Zhang Zhonyu Duan

【机构】

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DepartmentofPolymerScienceandEngineering,HebeiUniversityofTechnology,Tianjin,300130,China

【出处】

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The 6th International Symposium on Polymer Chemistry(2014年第六

【发表日期】

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2014年6期

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In present work,we report a facile access to prepare stereopolyester with tunable geometric structure through the organocatalytic copolymerization of cyclohexene oxide (CHO) with norbornene anhydride (NA) stereoisomers.(see Scheme 1) The focuses have been devoted to determine the influence of NA configuration on the copolymerization under various conditions,in particular on the stereochemistry of resulting polyester as well as their properties.Moreover,to evaluate versatility of resulting polyester,a free radical-mediated thiol-ene reaction was employed to testify the capacity.

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FACILE APPROACH FOR THE CONTROLLABLE SYNTHESIS OF STEREOREGULAR POLYESTER FROM ORGANOCATALYTIC EPOXI

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