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We develop a new theory to connect two areas:(ⅰ)Painlev(e)Ⅵ equation and(ⅱ)the mean field equation with multiple singular sources on tori.This gives a geometric interpretation of solutions to Painlev(e)Ⅵ equation with some special parameters.We establish this theory by applying a generalized Lam(e) equation(a linear ODE).As an application,we obtain a sharp existence result for the mean field equation on tori.This is a joint work with Professors Chang-Shou Lin and Ting-Jung Kuo.