【摘 要】
：
The concept of "cooperative catalysis" has been recognized as one of the most powerful approaches for stimulating innovations to revolutionize the processes
【机 构】
：
StateKeyLaboratoryofOrganometallicChemistry,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofScie
【出 处】
：
中国化学会全国第十一届有机合成化学学术研讨会
论文部分内容阅读
The concept of "cooperative catalysis" has been recognized as one of the most powerful approaches for stimulating innovations to revolutionize the processes of pharmaceutical, material and chemical industries,[1] In this talk, several case studies in our lab on the design of highly efficient molecular catalysts and the development of new sustainable processes on the basis of "cooperative catalysis" will be presented, including an integrated Salen/M catalyst for asymmetric cyanation of aldehydes,[2] a bifunctional SKP/Pd catalyst for asymmetric allylic amination of MBH adducts,[3] and anew process from CO2 to methanol via a hydrogenation of ethylene carbonate under mild conditions (Scheme 1).
其他文献
Molecular dynamics (MD) method is an important simulation tool, but its results are always doubtful due to its unrealistic high strain rates.In this paper, a hy
Co3O4/graphene oxide (GO) nanocomposites were successfully prepared by a depositing-decomposition method.The as-prepared samples were characterized by scann
As an atom-efficient method, the Tishchenko reaction has been used for the preparation of dimeric esters in industry1-2.A number of catalysts for the Tishchenko
Single-site early transition metal catalysts have been extensively investigated for the polymerization of nonpolar olefins.1 On the other hand, there are some i
In asymmetric conjugate additions (ACA), excellent regio-and stereo-selectivities have been achieved in reactions involving transition metal-catalyzed α,[β-un
Substituted pyrrolyl as a supporting ligand with various metals has attracted increasing attention by virtue of its strong metal-ligand bonds and exceptional tu
New half-sandwich scandium complexes bearing thiophen or pyrrole-fused cyclopentadienyl ligands were facilely synthesized by alkane elimination reaction of Sc(C
In stark contrast with Zn or even Mg, only a handful of efficient ROP single-site initiators based on the larger alkaline-earth metals (calcium, strontium and b
A novel gem-difluoromethylenated oleanolic acid was synthesized and its anti-hepatocellular carcinoma activity in vitro was tested.The results of biological
1,5-苯并二氮杂卓类衍生物是一类具有重要药理活性和生理活性的七元含氮杂环化合物1,根据国内外文献报道,其具有抗惊厥、抗焦虑、抗抑郁、镇静、止痛等作用,在医学上常用作镇