Quantitative Estimation of Reaction Rate Constants only Using One Physical Parameter for Each Reacta

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It is well known that for a chemical reaction,such as electron-,proton-,hydrogen atom-,hydride-,and group-transfer reactions(eq 1),it has been a chemists dream for a century that the reaction rate constant like the corresponding thermodynamic driving force can be quantitatively estimated only using one physical parameters for each reactant.
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