Cu(Ⅰ)/Ag(Ⅰ)-Mediated Decarboxylative Trifluoromethylation of Aryl Propiolic Acids with Me3SiCF3 at R

来源 :第十四届全国均相催化学术讨论会 | 被引量 : 0次 | 上传用户：kyuiyigjghj

【摘要】

：

The trifluoromethyl derivatives are widely used in agrochemicals,pharmaceuticals and materials,[1-4] since incorporation of trifluoromethyl groups into the organic molecules brings remarkable changes

【作者】

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Lingling Yang Yajun Xu Ping Huang Wenxing Wang Yaming Li

【机构】

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State Key Laboratory of Fine Chemicals,School of Chemical Engineering,Dalian University of Technolog

【出处】

：

第十四届全国均相催化学术讨论会

【发表日期】

：

2015年7期

【关键词】

：

Trifluoromethylation Arylpropiolicacids Trifluoromethylatedacetylenes Cu(Ⅰ)/Ag(Ⅰ

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The trifluoromethyl derivatives are widely used in agrochemicals,pharmaceuticals and materials,[1-4] since incorporation of trifluoromethyl groups into the organic molecules brings remarkable changes in their physical,chemical,and biological properties because of the strong electronic properties,lipophilicity and metabolic stability of the trifluoromethyl group.

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Cu(Ⅰ)/Ag(Ⅰ)-Mediated Decarboxylative Trifluoromethylation of Aryl Propiolic Acids with Me3SiCF3 at R

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