玻璃表面4-乙烯吡啶的接枝聚合

来源 :河南省化学会2018年学术年会 | 被引量 : 0次 | 上传用户：liongliong524

【摘要】

：

本文采用氮氧稳定自由基聚合方法在玻璃表面制备了4-乙烯吡啶聚物刷(P4VP),制备过程包含以下几个步骤：(ⅰ将)3-甲基丙烯酰氧基丙基三甲氧基硅烷接枝到玻璃表面；(ⅱ)将以过氧化二苯甲酰(BPO)引发剂,引发3-甲基丙烯酰氧基丙基三甲氧基硅烷末端上的双键产生自由基,进而将2,2,6,6-四甲基哌啶-N-氧基-1-羟基(HTEMPO·)铆接在玻璃表面；(ⅲ在)HTEMPO· 存在下,引发4-乙烯吡啶

【作者】

：

雷李玲陈志军韩红卫

【机构】

：

郑州轻工业学院材料与化学工程学院,河南省表界面重点实验室,郑州450001

【出处】

：

河南省化学会2018年学术年会

【发表日期】

：

2018年10期

【关键词】

：

活性自由基聚合聚合物"刷子" 3-甲基丙烯酰氧基丙基三甲氧基硅烷紫外吸收光谱

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玻璃表面4-乙烯吡啶的接枝聚合

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