【摘 要】
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Podands, a term coined by V(o)gtle and Weber in 1979,[1] refer to the acyclic supramolecular hosts which containing a polyether backbone and two terminal groups.Like their cyclic counterparts, podands
【机 构】
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Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and
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Podands, a term coined by V(o)gtle and Weber in 1979,[1] refer to the acyclic supramolecular hosts which containing a polyether backbone and two terminal groups.Like their cyclic counterparts, podands can form curled rigid conformations by the association with a suitable metal cation.The terminal groups are thus brought close, significantly increasing their interactions.[2] Despite achievements in allosteric systems and responsive materials, the applications of podands in catalysis are rarely reported,[3] especially for asymmetric catalysis.
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