Characterization of sorption stability of Cd(Ⅱ) on palygorskite comprehensive approaches

来源 :The 17th International Conference on Heavy Metals in the Env | 被引量 : 0次 | 上传用户:caoda0512116
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  Despite the widespread use of clay minerals as immobilization reagents for the remediation of heavy-metal-polluted soil,there is limited information on the remediation stability.Sorption stability is considered essential for remediation stability.In this study,therefore,the sorption stability in an ideal solid solution system was investigated using palygorskite(PAL)and cadmium as models.The sorption and desorption behaviors of Cd(Ⅱ)on PAL,including isotherms,kinetics,and various contributing factors(pH,temperature,background electrolytes,and environmental conditions)were studied.The maximum sorption amount was approximately 40 mg/g; the Langmuir isotherm and second kinetic model were the best fits to the sorption process.The thermodynamic parameters calculated from the sorption data at different temperatures indicated that the sorption of Cd(Ⅱ)on PAL was endothermic and favored at higher temperatures.The minimal desorption caused by water and acidic solutions implied that irrigation or runoff and acid rain may have weak effects on sorption.The temperature,pH,and background electrolyte dependence confirmed that the sorption of Cd(Ⅱ)on PAL was stable.The study demonstrated that sorption of Cd(Ⅱ)on PAL was stable under the simulated environmental conditions.The sorption mechanisms were found to involve surface precipitation of CdCO3 and surface complexation with hydroxyl groups.
其他文献
化学需氧量(COD)是反映水体受有机污染程度的重要指标之一,也是水质监测的一个重要项目,COD测定过程中玻璃器皿的洗涤、标准溶液的贮存与标定、回流温度与时间、干扰离子的消
建设项目竣工验收监测中工况监督决定了监测数据的有效性.根据建设项目规范的有关要求,结合工作实践,探讨了不同项目竣工环保验收监测中工况监督的要点.生产负荷的确定是验收
环境预警监测能有效预防、及时控制和消除环境污染事件.因此为了加强环境预警监测功能,建议提高技术装备水平和监测人员自身素质,保证监测数据的准确性,预防为主,确立常态管理意
从运作方式的选择、现场负责人职责的转变、第三方现场监测人员的岗前培训的重点、《第三方监测机构人员现场监测管理办法》制定的指导思想和内容4个方面,阐述了环境监测站引
  通过对比粘胶基纤维粘J系列的J-10,J-12和沥青纤维丝A 系列的A-10,A-20的比表面积、微孔结构及挂膜后生物活性指数的变化情况,确定了最佳的活性炭纤维(ACF)载体材料为J-1
在对突发环境事件特性简单介绍的基础上,分析了现有县级环境监测站在应急监测方面存在的问题,建议县级环境监测站加强应急监测机制建设,提高应急监测水平,提高应急监测能力的硬
  Heavy metal pollution of the cultivated area is one of the most actual problems today.It is available numerous data which has demonstrated that the applicat
  To investigate the variations of shoot PAEs(DBP and DEHP)concentration among 28 Chinese flowering cabbage cultivars and to determine the differences in subc
  Segara Anakan is a coastal lagoon located in south central Java,Indonesia,where large mangrove areas are still observed.In recent decades,this lagoon has un
  A total of 42 agricultural soil samples were collected near E-waste recycling workshops.And concentrations and sources of seven heavy metals(Cd,Cr,Cu,Hg,Ni,