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Gold(Ⅰ)-catalysis has received much attention and made much progress in past decade, due to their strong carbophilic Lewis acidity.However, the control of selectivity especially the enatioselectivity of gold catalyzed reaction still poses considerable challenges due to the linear binding mode.During the past 5 years, we have developed a rich variety of new synthetic methods under the catalysis of gold(Ⅰ).These reactions aimed at the efficient construction of carbo-and heterocycles, especially furans and pyrroles fused ring systems, featured with the following issues: 1) new understanding of the difference between the carbophilic gold catalysts and the oxophilic Lewis catalysts; 2) selective synthesis from those substrates with multifunctional groups; 3) synthesis of different products from the same starting material(s) by suitable choice of different catalysts; and 4) in-depth investigations of reaction mechanisms and then design of novel cycloaddition or cyclization reactions (Figure 1).