A novel MOF with double helical chains based rigid tripodal ligands: syntheses,crystal structures,an

来源 :2016年中西部地区无机化学化工学术研讨会 | 被引量 : 0次 | 上传用户:lqlq2323
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  A three-dimensional metal-organic framework (MOF),namely [Cd2(BPDB)2(H2O)]n (1) (2,6-di-p-carboxyphenyl 4,4'-bipyridine1=H2bpydb) has been solvothermal synthesized and characterized by elemental analysis,FT-IR spectroscopy andX-ray diffraction.
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  A new compound,{[Co(bmzbc)2]·2DMF}n (JXNU-1,JXNU denotes Jiangxi Normal University),based on the 4-(benzimidazole-1-yl)benzoate (bmzbc-) ligand has been sy
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  金属-有机框架材料(MOFs)具有比表面积大、结构可控、孔径大小可调等优点。同时,MOFs中的有机配体通常具有比无机材料更高的光学吸收系数,能有效提高材料对光能的利用效
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  Crystal structure of metal borates has been extensively investigated by X-ray and neutron diffraction,etc.Very complicated structure studies in aqueous poly
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  设计合成了一种抗磁性质的二环[2.2.2]辛二烯取代铜(Ⅲ)咔咯分子,该分子在真空加热升华至金的表面时,通过逆Diels-Alder反应失去乙烯分子,直接定量转变为具有顺磁性的苯并铜
  Nitroaromatic compounds (NACs) are a source of pollution for groundwater and soils due to their explosively and high toxicity [1].
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  By adjusting the pH value of the system,the tetra-nuclear Zn(Ⅱ)-DNA-schiff base complexes {[Zn2ClLn(en)]2 (C8H4O4)} (fig.1) (L1 = D11-4M-D12-4M,L2 = D11-4H
  As an important multifunctional ligand,organic aromatic polycarboxylate,especially aromatic tetracarboxylate,have emerged as ideal linkers for building meta
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  The rational design and construction of metal-organic frameworks have received considerable attention over the past decade because of their interesting vari
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