论文部分内容阅读
Transition metal-catalyzed hydroarylation have become one of the most powerful tools for the construction of C-C bond.Particularly,the iridium complexes have emerged as efficient catalysts for this type of transformation.In this context,Nishimura and co-workers very recently developed a hydroarylation of alkenyl ethers catalyzed by an Ir/chiral bisphosphine complex[1],where the aryl groups were selectivity installed at the α-carbon atom to the alkoxyl group with high enantioselectivity(Figure 1).