【摘 要】
：
配位聚合物从广义上可以定义为无机—有机杂化材料,兼具金属络合物和有机高分子化合物两者特点,既有良好的稳固性又能呈现丰富多样的结构和性质,在吸附分离、荧光感应、异相催化、新能源等诸多领域展现出广阔的应用前景。多齿羧酸配体具有多个配位点、配位能力强、配位模式丰富多样化,与金属离子通过配位键结合和超分子相互作用易产生多核多维框架结构,成为研究者关注的焦点。本论文设计合成了四种(H_4BTEC=1,2,3
论文部分内容阅读
配位聚合物从广义上可以定义为无机—有机杂化材料,兼具金属络合物和有机高分子化合物两者特点,既有良好的稳固性又能呈现丰富多样的结构和性质,在吸附分离、荧光感应、异相催化、新能源等诸多领域展现出广阔的应用前景。多齿羧酸配体具有多个配位点、配位能力强、配位模式丰富多样化,与金属离子通过配位键结合和超分子相互作用易产生多核多维框架结构,成为研究者关注的焦点。本论文设计合成了四种(H_4BTEC=1,2,3,5-苯四甲酸、H_3BITRC=3,4,5-联苯三甲酸、H_5BIPEC=3,4,5,3’,5’-联苯
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