超临界乙醇流体制备TiO2光催化剂(Ⅰ)合成与光催化性能

来源 :化工学报 | 被引量 : 0次 | 上传用户:yilishabai123
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Photo-catalytic TiO 2 was prepared from tetraisopropyl titanate (TPT) in supercritical ethanol. It was found that TPT in supercritical ethanol could be effectively converted into the anatase-form of TiO 2 crystallites. The anatase-form of TiO 2 as a photo-catalyst was evaluated for its adsorptivity and subsequent photo-catalytic activities on formaldehyde, one of the harmful air pollutants in the environment. As a result, the supercritically treated TiO 2 had a high decomposing ability. Under the same condition, the experiment was repeated for 5 times,and photocatalysis of the samples did not decrease. This indicated that the supercritical treatment was effective to prepare photo-catalytic TiO 2, which was feature by stability, longevity and high photo-catalytic decomposition of formaldehyde for environmental cleaning. Meanwhile, unlike conventional chemical reaction, which is complex and time-consuming, supercritical treatment is easy to operate, saving both time and labor. It was found that TPT in supercritical ethanol could be effectively converted into the anatase-form of TiO 2 crystallites. The anatase-form of TiO 2 as a photo- catalyst was evaluated for its adsorptivity and subsequent photo-catalytic activities on formaldehyde, one of the harmful air pollutants in the environment. As a result, the supercritically treated TiO 2 had a high decomposing ability. Under the same condition, the experiment was repeated for 5 times, and photocatalysis of the samples did not decrease. This indicates that the supercritical treatment was effective to prepare photo-catalytic TiO 2, which was featured by stability, longevity and high photo-catalytic decomposition of formaldehyde for environmental cleaning. Meanwhile, unlike conventional chemical reaction, which is complex and time-consuming, supercritical treatment is easy to operate, saving both time and labor.
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