T The title compound, 4-amino-3-(p-chlorophenyl)-5-(p-methoxybenzyl)-4H-1,2,4-triazole I, CHCINO), has been determined using X-ray diffraction techniques and the molecular structure has also been optimized at the B3LYP/6-31 G(d, p)level using density functional theory (DFT). The triazole ring exhibits dihedral angles of 41.61(15)°and 80.73(11)° with the phenyl rings.and a triazole N atom, forming C(5)chains which are further linked to give a two-dimensional network of molecules.The N-H…N hydrogen bonding is supported by C-H…N hydrogen bond and C-H…π interaction.Intermolecular N-H…N and C-H…N hydrogen bonds produce R22(9),R44(10)and R