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The title complex [RuH(CO)(PPh3)2(4-ClPhNHCS2)]·C6H14 has been prepared and characterized by X-ray diffraction analysis.It crystallizes in the triclinic system,space group P1 with a = 11.0817(2),b = 14.3889(2),c = 15.2136(2) ,α = 71.018(1),β = 74.911(1),γ = 85.146(1)°,V = 2214.86(6) 3,Z = 2,Mr = 900.4,Dc = 1.350 g/cm3,Mr = 900.40,μ(MoKα) = 0.616 mm-1,F(000) = 926,S = 1.016,the final R = 0.0478 and wR = 0.0947 for 6828 observed reflections with I > 2σ(I) and 505 variables.The molecular structure of 1 consists of one neutral complex [RuH(CO)(PPh3)2(4-ClPhNHCS2)] and one hexane solvent molecule.The geometry around ruthenium is pseudo-octahedral with two trans-binding PPh3 ligands and one chelating bidentate 4-ClPhNHCS2- ligand via two sulfur atoms.The average Ru-S,Ru-P and Ru-H bond lengths are 2.4824(8),2.3495(8) and 1.71(2),respectively.The electrochemical properties of 1 have been studied in CH2Cl2 solution by cyclic voltammetry.
The title complex [RuH (CO) (PPh3) 2 (4-ClPhNHCS2)] C6H14 has been prepared and characterized by X-ray diffraction analysis. It crystallizes in the triclinic system, space group P1 with a = 11.0817 a = 71.018 (1), β = 74.911 (1), γ = 85.146 (1) °, V = 2214.86 (6) 3, Z = 2, Mr = 900.4, Dc = 1.350 g / cm3, Mr = 900.40, μ (MoKα) = 0.616 mm -1, F (000) = 926, S = 1.016, the final R = 0.0478 and wR = 0.0947 for 6828 observed reflections with I> 2σ (I) and 505 variables. The molecular structure of 1 consists of one neutral complex [RuH (CO) (PPh3) 2 (4-ClPhNHCS2)] and one hexane solvent molecule.The geometry around ruthenium is pseudo-octahedral with Two trans-binding PPh3 ligands and one chelating bidentate 4-ClPhNHCS2-ligand via two sulfur atoms. The average Ru-S, Ru-P and Ru-H bond lengths are 2.4824 (8), 2.3495 (8) and 1.71 , respectively. The electrochemical properties of 1 have been studied in CH2Cl2 solution by cyclic voltammetry.