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用新合成法制备的新型配体三苯基乙荒酸四乙基铵盐(Ⅰ)和 AgNO_3在不同条件下反应分别获得单核银络合物Et_4N~+[Ag(Ph_3CCS_2)_2]~-·2 THF(晶体Ⅱ)和六核银簇合物Ag_6(Ph_3CCS_2)_6·Py.6DMF(晶体Ⅲ)。用X射线单晶衍射法测定了它们的晶体结构。
The novel ligands tetrakisethylammonium triphenylphosphoric acid (Ⅰ) and AgNO 3 were synthesized by the new synthesis method to obtain mononuclear silver complexes Et_4N ~ + [Ag (Ph_3CCS_2) _2] · 2 THF (crystal Ⅱ) and hexagonal silver cluster Ag_6 (Ph_3CCS_2) _6 · Py.6DMF (crystal Ⅲ). Their crystal structures were determined by X-ray single crystal diffraction.