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对於葛氏試剂在乙醚溶液中的电化学性貭,Konduirev,W.V.Evans和李方訓等做过若干研究;包括电导,电輸数与电解等工作,闡明了它的若干电性貭与它的结构和化学性貭有关系。 1.电导:葛氏試剂在乙醚溶液里具有电解貭的导电性质。Kondyrew & Manjew测量过EtMgBr在不同溫度时的电导。Kondyrew & Ssusi研究了EtMgI的电导的稀釋效应。Evans & Lee測量了几种葛氏試剂的乙醚溶液在不同溫度与不同濃度时的电导,得到EtMgBr的电导最大。且电导大小的次序为:
Several studies have been done on the electrochemical properties of Ge’s reagent in ether, Konduirev, WVEvans, and Li Fangxun et al., Including conductance, electrical losses, and electrolysis, clarifying some of its electrical properties and its Structure and chemical properties have a relationship. 1. Conductivity: Ge’s reagent has the conductive properties of Electrolyte in ether solution. Kondyrew & Manjew measured the conductance of EtMgBr at different temperatures. Kondyrew & Ssusi studied the conductance dilution effect of EtMgI. Evans & Lee measured the conductance of several Grignard reagent solutions of ether at different temperatures and concentrations, resulting in the highest conductance of EtMgBr. And the order of conductance size is: