导向的过渡金属催化芳烃C—H官能化反应是近年来发展起来的一种非常重要的芳烃定向官能化方法,然而,其固定的邻位活化模式限制了该方法的广泛应用.因此,发展一种导向的过渡金属催化的适用于芳烃“任意”位置,包括邻位、间位、对位以及苄位C—H的官能化方法,是非常具有挑战性的研究课题.芳胺及其衍生物在医药、农药、 Guided transition metal-catalyzed C-H functionalization of aromatics is a very important aromatic orientation functionalization method developed in recent years, however, its fixed mode of ortho-activation limits the wide application of this method. Therefore, Catalytic transition metal-catalyzed functionalization of aromatics at the “arbitrary” position, including the ortho, meta, para and para-C-H functionalities, is a very challenging research topic. Derivatives in medicine, pesticides,