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标题化合物{[Cu(C18H17N3O2)]2(COO)}(ClO4).3H2O(1)由Cu(ClO4)2.6H2O甲酸、水杨醋缩4-氨基安替吡啉经溶剂热反应得到,用单晶衍射法测定了配合物的结构,具体测定结果如下:单斜晶,空间群P2/c,a=15.1500(2),b=23.8857(11),c=12.9709(4),β=107.265(3)°,V=4482.3(3)3,Dc=1.349g/cm3,Z=4,Mr=910.28,μ=1.066mm-1和F(000)=1872,最终偏差因子分别为R1=0.0924,wR2=0.2514。在此晶体结构中,2个铜离子被COO-和苯酚氧桥联形成二聚单元,每个Cu(Ⅱ)是五配位的变形四方锥构型。
The title compound {Cu (C18H17N3O2) 2 (COO)} (ClO4) .3H2O (1) was obtained by solvothermal reaction of Cu (ClO4) 2.6H2O / The structure of the complex was determined by single crystal diffraction method. The specific results are as follows: monoclinic space group P2 / c, a = 15.1500 (2), b = 23.8857 (11), c = 12.9709 (4) 107.265 (3) °, V = 4482.3 (3) 3, Dc = 1.349g / cm3, Z = 4, Mr = 910.28, μ = 1.066mm-1 and F (000) = 1872. The final deviation factors are R1 = 0.0924, wR2 = 0.2514. In this crystal structure, two copper ions are bridged by COO- and phenol oxygen to form dimeric units, and each Cu (II) is a five-coordinate deformed tetragon cone configuration.