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热力学基础是物理化学课程中重要的部分。但目前关于这一部分的讲授有着不同的方式。我们读了吴澄铠同志的文章(化学通报1954年10月号)后,有一些不很成熟的意见,希望英澄铠同志和其他同志指教。 (1)吴澄铠同志在该文第(一)项“关于第一定律的实验根据问题”中,提到:“将第一定律的数学公式(即(△μ=q-A)和它的实验根据用严密的逻辑结合起来”这一问题,所用的方法是:“首先从历史上找寻恒动机失败的经验,来说明能量不能够从无中生出来,但是这还不能令人信服,因为以往做不出来,将来也许还可以做出来。直到焦尔的实验证明了能量消失时必然有热生出来,而且消失的能量和生出的热量的比,在不同的情况下,都保持同一的常数。这样才说明热量也是能量的一种,并
The basis of thermodynamics is an important part of the course of physical chemistry. But there are different ways to teach this part right now. After reading the article by Comrade Wu Cheng-kai (Bulletin of Chemical Weapons, October 1954), we have some unrealistic opinions and hope that Comrade Ying Cheng-kai and other comrades will enlighten. (1) Comrade Wu Cheng-kai mentioned in Item (1) of the article “Experimental Basis on First Law” that “the mathematical formula of the first law (ie, (△ μ = qA) and its experimental basis Tight logic, ”the approach used is:" First, look at the history of the experience of failure of a permanent motive to show that energy can not be absent, but this is not yet convincing, because in the past do not May come out in the future may be able to do until Jol’s experiment proved that the disappearance of energy will inevitably have a spontaneous birth, and the disappearance of energy and calorie generated than in different circumstances, to maintain the same constant That heat is also a kind of energy, and