【摘 要】
：
The chain [ Cu2I2(PPh3)2(C4H5N3)] has been synthesized and characterized by X-ray crystallography.It crystallizes in the triclinic system,space group P 1,with
【机 构】
：
Department of Chemistry, Capital Normal University,Beijing 100037,China,Department of Chemistry, Cap
【出 处】
：
Chinese Journal of Chemistry
论文部分内容阅读
The chain [ Cu2I2(PPh3)2(C4H5N3)] has been synthesized and characterized by X-ray crystallography.It crystallizes in the triclinic system,space group P 1,with a=0.9985(2)nm,b=1.0998(2)nm,c=1.5174(2)nm,a=87.89(1),P=76.73(l),7=77.77(1),V=1.5849(5)nm3,Z=2,Bc=2.095g/cm3 [Gu2I2(PPh3)2(Crh5N3)] has a dimmer unit [Cu2I2(PPh3)2(C4H5N3)].The two N atoms of the phenyl ring of 2-aminopyrimidine bridge two [CuI(PPh3)]2 units,by which a one-dimensional chain is constructed.The van der Waals force makes the molecules arrange in the three-dimensional space.
The chain [Cu2I2 (PPh3) 2 (C4H5N3)] has been synthesized and characterized by X-ray crystallography. It crystallizes in the triclinic system, space group P 1 with a = 0.9985 (2) nm, b = 1.0998 (1), V = 1.5849 (5) nm3, Z = 2, Bc = 2.095 g / cm3, and nm = 1.5174 nm, a = 87.89 (1), P = 76.73 (1), 7 = 77.77 The two N atoms of the phenyl ring of 2-aminopyrimidine bridge two [CuI (PPh3)] 2 units, which which a (PPh3) 2 (Crh5N3)] has a dimmer unit [Cu2I2 (PPh3) 2 (C4H5N3) one-dimensional chain is constructed. The van der Waals force makes the molecules arrange in the three-dimensional space.
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