论文部分内容阅读
超分子自组装是发展超分子电子学的重要途径。随着纳米科学和技术的迅速发展,自组装技术已成功地应用于纳米尺度物质的维数、形貌和功能等的调控。作为构筑分子水平上一维、二维、三维有序功能结构和高有序分子聚集态结构的关键技术,超分子自组装技术有力地推动了具有优良光、电、磁性能的分子材料和纳米功能材料更深层次的研究。本文综述了超分子自组装在富勒烯科学领域的基础研究和应用,特别是对有利于自组织和自组装功能的富勒烯基衍生物的设计与合成、超分子作用力引导的具有特定结构的分子体系的可控自组装、以及富勒烯分子聚集态结构材料的光物理过程、超分子中电子转移和能量转移现象进行了描述;并对卟啉、四硫富瓦烯、碗烯和杯芳烃等一系列富π电子化合物和大环主体分子等包含[60]富勒烯的主体化合物的超分子作用和超分自组装体以及通过氢键、π-π作用、静电力和范德华力和金属配位作用形成的[60]富勒烯超分子自组装体进行了总结,对未来发展进行了展望。
Supramolecular self-assembly is an important way to develop supramolecular electronics. With the rapid development of nanoscience and technology, self-assembly technology has been successfully applied to the regulation of the dimension, morphology and function of nanoscale materials. As one of the key technologies to construct one-dimensional, two-dimensional, three-dimensional ordered functional structures and high ordered molecular aggregation states at the molecular level, supramolecular self-assembly technology has promoted the molecular materials with excellent optical, electrical and magnetic properties and nano A deeper study of functional materials. This review summarizes the fundamental research and applications of supramolecular self-assembly in the field of fullerene science. In particular, the design and synthesis of fullerene-based derivatives that facilitate self-assembly and self-assembly, supramolecular force- Controlled self-assembly of the molecular structure of the structure, and the photophysical process of the fullerene molecularly aggregated structure material, electron transfer and energy transfer phenomena in supramolecules. The effects of porphyrin, tetrathiafulvalene, And calixarenes and a series of rich π-electron compounds and macrocyclic host molecules and other host compounds containing [60] fullerenes Supramolecular and super-self-assembly and hydrogen bonding, π-π interaction, electrostatic force and Van der Waals The [60] fullerene supramolecular self-assembly formed by the interaction of metal ions and metal ions was summarized and the future development was prospected.