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A series of novel rhenium(Ⅰ) 2,2'-bipyridyl complexes [fac-Re(4,4'-di-COOEt-bpy)-(CO)3(Xpy)PF6], where bpy is 2,2'-bipyridine, py is pyridine and X is 3-methyl, 3-hydroxy, or3-amino, were synthesized, their photophysical and electrochemical pr