Adsorption of Mn2+ from aqueous solution using Fe and Mn oxide-coated sand

来源 :Journal of Environmental Sciences | 被引量 : 0次 | 上传用户:pyking2003
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
The adsorption of Mn2+ onto immobilized Mn-oxide and Fe-oxide adsorbent such as manganese oxide-coated sand 1 (MOCS1), manganese oxide-coated sand2 (MOCS2), iron oxide-coated sand2 (IOCS2), and manganese and iron oxide-coated sand (MIOCS)was investigated. The effects of pH (5.5 to 8.0) and temperature (25 to45°C) on the equilibrium capacitywere examined. Equilibrium studies showed that there is a good fitwith both Freundlich and Langmuir isotherm,which indicates surface heterogeneity and monolayer adsorption of the adsorbents. Kineticdata showed high correlationwith the pseudo second-order model,which signifies a chemisorption-controlled mechanism. The activation energies, activation parameters (ΔG*,ΔH*,ΔS*), and thermodynamic parameters (ΔG0 , ΔH0 , ΔS0 ) confirmed that adsorptionwith MIOCSwas endothermic and more spontaneous at higher temperaturewhile an opposite trendwas observed for the other adsorbents. Thermodynamic studies showed that adsorption involved formation of activated complex,where MOCS1 and MIOCS follow a physical-chemical mechanism,while MOCS2 and IOCS2 follows purely chemical mechanism. The adsorption of Mn2 + onto immobilized Mn-oxide and Fe-oxide adsorbent such as manganese oxide-coated sand 1 (MOCS1), manganese oxide- coated sand2 (MOCS2), iron oxide- coated sand2 (IOCS2), and manganese and iron oxide- The effects of pH (5.5 to 8.0) and temperature (25 to 45 ° C) on the equilibrium capacitywere examined. Equilibrium studies showed that there is a good fitwith both Freundlich and Langmuir isotherm, which indicates surface heterogeneity The activation energies, activation parameters (ΔG *, ΔH *, ΔS *), and thermodynamic parameters (ΔG0, ΔH0 , ΔS0) confirmed that adsorption with MIOCSwas endothermic and more spontaneous at higher temperaturewhile an opposite trendwas observed for the other adsorbents. Thermodynamic studies showed that adsorption involved formation of acti vated complex, where MOCS1 and MIOCS follow a physical-chemical mechanism, while MOCS2 and IOCS2 purely chemical mechanism.
其他文献
粉喷桩作为一种新型的软土处理方法,优点明显,应用领域也越来越广泛.本文结合桥梁工程实例,阐述粉喷桩加固软土地基的优点及原理、施工工艺流程,并提出了质量保证措施,处理后
期刊
该文从挂篮荷载计算、施工流程、支座及临时固结施工、挂篮安装及试验、合拢段施工、模板制作安装、钢筋安装、混凝土的浇筑及养生、测量监控等方面人手,介绍了S226海滨大桥
期刊
本文通过对荣华二采区10
期刊
该文从挂篮荷载计算、施工流程、支座及临时固结施工、挂篮安装及试验、合拢段施工、模板制作安装、钢筋安装、混凝土的浇筑及养生、测量监控等方面人手,介绍了S226海滨大桥
期刊
园林景观设计作为景观建设的第一个阶段,对景观项目的推进与实施起着尤为重要的作用.施工是将园林设计理念变为现实的过程,施工方在施工前没有与设计人员充分沟通,对工程创作
该文从挂篮荷载计算、施工流程、支座及临时固结施工、挂篮安装及试验、合拢段施工、模板制作安装、钢筋安装、混凝土的浇筑及养生、测量监控等方面人手,介绍了S226海滨大桥
随着社会的发展,城市化快速发展,建筑业得到了良好的发展机会,在建筑工程如雨后春笋般出现的同时,也存在着不容乐观的问题,建筑工程的建设导致了资源的过度消耗和环境压力的