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对金属有机络合物Zn(NH_2CSNHNH_2)Cl_2(简称TSCZC)的晶格振动进行了群论对称性分类,在各种不同的几何配置下获得其偏振喇曼散射;对其中主要峰的归属进行了分析认定;与Ca(NH_2CSNHNH_2)Cl_2单晶的喇曼谱进行了对照,分析了二者存在较大差异的原因。
The lattice vibration of the metal organic complex Zn (NH_2CSNHNH_2) Cl_2 (TSCZC) has been systematically and symmetrically classified, and its polarization Raman scattering has been obtained under various geometrical configurations. The assignment of the main peaks It is analyzed and compared with the Raman spectrum of Ca (NH_2CSNHNH_2) Cl_2 single crystal, and the reason why there is a big difference between them is analyzed.