基于棱烷的发展历程,详细叙述了三棱烷、立方烷、五棱烷和六棱烷及其衍生物等笼状结构化合物的合成路线及特点,介绍了基团贡献法和量子化学方法在棱烷理论计算中的应用,并对其研究进展和应用前景进行了评述。 Based on the history of the development of ethane, the synthetic route and characteristics of the cage compounds such as trilenes, pentanes, pentasilanes and hexaalkanes and their derivatives were described in detail. The group contribution method and quantum chemistry method were introduced The application of the theory in the calculation of alane and its research progress and application prospect are reviewed.