【摘 要】
：
合成了标题化合物。该化合物的分子式[Ni(Br2TSSB)(Bipy)(H2O)]0.86C2H5OH (C20.72H22.15- Br2NiN3O5.86S), 分子量657.47, 采用单色化的MoK?( = 0.071073 nm)射线测定, 共收
【机 构】
：
广西师范大学化学化工学院,桂林工学院材料与化学工程系,广西师范大学化学化工学院,广西师范大学化学化工学院,桂林工学院材料与化学工程系 桂林541004,湛江海洋大学应化系,广东湛江524088,广西桂
论文部分内容阅读
合成了标题化合物。该化合物的分子式[Ni(Br2TSSB)(Bipy)(H2O)]0.86C2H5OH (C20.72H22.15- Br2NiN3O5.86S), 分子量657.47, 采用单色化的MoK?( = 0.071073 nm)射线测定, 共收集10615个数据, 其中独立衍射点4709个 (Rint = 0.0258), I > 2(I)可观测点数1658个, 结果表明该化合物属单斜晶系,空间群C2/c, 其晶胞参数: a = 1.9930(6), b = 1.4033(4), c = 1.9872(5) nm, ?= 110.70(2), V = 5.199(3) nm3, Z = 8, Dc = 1.680 g/cm3 , m = 3.940 mm-1, F(000) = 2626, S = 0.805, Dr = 699 ~ 288 e/nm3. 该配合物是六配位的变形八面体构型。
The title compound was synthesized. The compound has the formula [Ni (Br2TSSB) (Bipy) (H2O)] 0.86 C2H5OH (C20.72H22.15- Br2NiN3O5.86S), molecular weight 657.47, collected by monochromatization of MoK? (= 0.071073 nm) The results showed that the compound belongs to monoclinic system with space group C2 / c and its unit cell parameters: a = 1.9930 (6), b = 1.4033 (4), c = 1.9872 (5) nm ,? = 110.70 (2), V = 5.199 (3) nm3, Z = 8, Dc = 1.680 g / cm3, mm-1, F (000) = 2626, S = 0.805, Dr = 699-288 e / nm3. The complex is a hexacoordinated deformed octahedral configuration.
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