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本文研究了在铜-铬-锌-锰氧化物催化剂上环戊二烯常压加氢的动力学。在一定条件下起始反应的动力学方程式可用下式表示。 r_0=k_0P_C~(0.5)P_H测定了反应的视活化能为12.4仟卡/克分子。讨论了反应的机理,动力学数据符合下列的机理式。 r_0=kK_CK_HP_H/(1+K_CP_C+K_HP_H)~2
In this paper, the kinetics of atmospheric hydrogenation of cyclopentadiene over copper-chromium-zinc-manganese oxide catalysts was investigated. Under certain conditions, the kinetic equation of the initial reaction can be expressed as follows. r_0 = k_0P_C ~ (0.5) P_H measured the apparent activation energy of 12.4 kcal / mole. The mechanism of reaction was discussed. The kinetic data conformed to the following mechanism. r_0 = kK_CK_HP_H / (1 + K_CP_C + K_HP_H) ~ 2