【摘 要】
:
Hybrid composite materials with hierarchical structures have attracted continuing attention for their enhanced features and various applications.The new hybrid composites XW9@PDA (XW9 means Na8 H[α-PW9O34],Na10[α-SiW9O34]and Na10[α-GeW9O34];PDA means poly
【机 构】
:
School of Public Health,Jilin University,Jilin 130021,China
论文部分内容阅读
Hybrid composite materials with hierarchical structures have attracted continuing attention for their enhanced features and various applications.The new hybrid composites XW9@PDA (XW9 means Na8 H[α-PW9O34],Na10[α-SiW9O34]and Na10[α-GeW9O34];PDA means polydopamine) have been synthesized for potential sensing applications.The effect of polyoxometalates on the formation of the hybrid composites was investigated.Scanning electron microscopy (SEM) supported the obtained XW9@PDA were hier-archical microsphere.By monitoring the reaction of classical peroxidase substrate o-phenylenediamine(OPD) to form yellow 2,3-diaminophenazine (DAB) in the presence of H2O2,the peroxidase-like activity of XW9@PDA was calculated.The results showed that XW9@PDA still keep the peroxidase-like activity and have 505.98%,208.58% and 582.78% enhancement in intrinsic catalytic activity for PW9@PDA,SiW9@PDA and GeW9@PDA.Among the three composites,PW9@PDA showed the highest peroxidase-like activity.Therefore,PW9@PDA was applicable to the colorimetric and electrochemical sensing for H2O2.
其他文献
Natural systems are typically featured with tremendous molecular complexity and construct exquisite architectures and functional materials through precise spatial and temporal control.Supramolecular self-assembly from peptides and proteins is believed to
Textile wastewater contains highly toxic,nondegradable,carcinogenic organic pollutants,causing severe damage to the ecological environment.In this work,β-cyclodextrin carbon-sphere-based nanocompos-ite (CS/SiO2@β-CD) with a core-shell-shell configuration
A cluster-based drag model is proposed for the gas-solid circulating fluidized bed (CFB) riser by including the cluster information collected from image processing and wavelet analysis into the calculation of system drag.The performance of the proposed dr
Semi-autogenous grinding (SAG) mill is widely used in the grinding process of coal and ores because of its strong applicability,large capacity and low consumption of grinding media.Therefore,the research of SAG mill is still of great important practical s
Designer biosurfactants can be used to stabilise and functionalise interfaces.One particularly promising use is the stabilisation of oil-in-water emulsions,enabling fine tuning physical,chemical and biological surface properties.The ability of emulsion sy
This paper studies a novel gas cyclone with a cylindrical filter face installed in the center from the vortex finder to the bottom hopper.The experimental results show that this composite cyclone has a higher collection efficiency and a lower pressure dro
The assembly of biomacromole particles with artificial solid matrixes to fabricate hybrid composites has been demonstrated as an efficient strategy to promote both components\' applications.Elaborating matrixes as well as appropriate assembly method is
The organic-inorganic hybrid composites displayed great potential for biotechnological and biomedical application.In this research,a gelatin/alginate/silica hybrid microsphere was developed by a synergy of membrane emulsification process and biomimetic mi
Pickering emulsions are emulsions stabilized by colloidal surfactants,i.e.solid particles.Compared with traditional molecular suffactant-stabilized emulsions,Pickering emulsions show many advantages,such as high resistance to coalescence,long-term stabili
Supercritical water (SCW) fluidized bed reactors convert biomass to fuels without pollutants emission.In this work,experimental studies were carried out to investigate voidage distribution in an SCW flu-idized bed by capacitance probes.Quartz sands with d