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Epitaxial BaTiO3 films with embedded metallic Ni nanocrystal (Ni-BaTiO3) were successfully fabricated on SrTiO3 (001) single-crystalline substrate through the laser molecular beam epitaxial (L-MBE) technique.High resolution transmission electron microscopy (HRTEM) and electron energy loss spectrum (EELS) with Kramers-Kronig analysis methods were employed to characterize the microstructures,elementary distribution and the electron structure of these films.HRTEM results suggested that the structure of BaTiO3 was tetragonal with lattice parameters of a=0.399 nm and c=0.403 nm.Energy dispersive X-Ray spectroscopy (EDX) confirmed metallic Ni nanocrystal embedded successfully in BaTiO3 epitaxial films.The Ni-BaTiO3 composite films were compound of the epitaxial BaTiO3 (110) layers alternating with Ni NCs array (111) layers.Furthermore,the existence of the misfit dislocations induced by the embedding of Ni nanoparticles was also clearly demonstrated by the HRTEM images.The Ni L2,3 edges of EELS revealed that Ni NCs in their metallic state were embedded uniformly in the BaTiO3 matrix.A chemical shift of about 7 eV regarding L3 edges in the Ni EELS was also observed.The optical band gap of BaTiO3 in these films was about 3.84 eV,higher than 3.55 eV for pure BaTiO3 films at room temperature.
Epitaxial BaTiO3 films with fabricated metallic nanocrystal (Ni-BaTiO3) were successfully fabricated on SrTiO3 (001) single-crystalline substrate through the laser molecular beam epitaxial (L-MBE) technique.High resolution transmission electron microscopy (HRTEM) and electron energy loss spectrum (EELS) with Kramers-Kronig analysis methods were employed to characterize the microstructures, elementary distribution and the electron structure of these films. HRTEM results suggested that the structure of BaTiO3 was tetragonal with lattice parameters of a = 0.399 nm and c = 0.403 nm . Energy dispersive X-Ray spectroscopy (EDX) confirmed metallic Ni nanocrystal embedded successfully in BaTiO3 epitaxial films. The Ni-BaTiO3 composite films were of the epitaxial BaTiO3 (110) layers alternating with Ni NCs array (111) layers. existence of the misfit dislocations induced by the embedding of Ni nanoparticles was also demonstrated by the HRTEM images. Ni L2, 3 edges of EE LS revealed that Ni NCs in their metallic state were uniformly uniformly embedded in the BaTiO3 matrix. A chemical shift of about 7 eV regarding L3 edges in the Ni EELS was also observed. than 3.55 eV for pure BaTiO3 films at room temperature.