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A novel visible light driven photocatalytic reactor with 54 7 pieces of Ag/AgBr-film-modified capillaries is reported and it is derived from a microstructured polymer optical fiber (MPOF) preform.The MPOF preform not only plays the role of a light-transmitting media,but it is also a Ag/AgBr supporting and waste-water pipe to supply the photocatalytic degradation of dyes solute.The photocatalytic reactor has such a large surface area for Ag/AgBr loading,which is a visible light driven photocatalyst that photodegradation e~ciency is enhanced.