Fabrication and photoelectrocatalytic properties of nanocrystalline monoclinic BiVO4 thin-film elect

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Monoclinic bismuth vanadate (BiVO4) thin film was fabricated on indium-tin oxide glass from an amorphous heteronuclear complex via dip-coating. After annealation at 400, 500, and 600℃, the thin films were characterized by X-ray diffraction, field emission scanning electron microscopy, X-ray photoelectron spectroscopy, and UV Vis spectrophotometry. The BiVO4 particles on the ITO glass surface had a monoclinic structure. The UV-Visible diffuse reflection spectra showed the BiVO4 thin film had photoabsorption properties,with a band gap around 2.5 eV In addition, the thin film showed high visible photocatalytic activities towards 2,4dichlorophenol and Bisphenol A degradation under visible light irradiation (λ>420 rum). Over 90% of the two organic pollutants were removed in 5 hr. A possible degradation mechanism of 2,4-dichlorophenol were also studied
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