Effect of Mn on microstructure of as-cast Ti47A18Nb(1~2)Mn alloys

来源 :Transactions of Nonferrous Metals Society of China | 被引量 : 0次 | 上传用户:yellow1989
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The microstructures of Ti47Al8NbxMn (mole fraction, %) alloy with x=1 or 2 were studied on as-cast, as-HIPped and on heat-treated samples. The results showed that Mn element is β phase stabilizer and promotes the formation of β(B 2) phase. B 2 phase exists at the dendrite cores of the as-cast microstructures. This phase is metastable and can completely decompose into α and(or) γ during 1 200 ℃, 200 MPa, 4 h HIP process. In the as-HIPed alloy with 1% (mole fraction) Mn addition, the α 2+γ lamellae structure is interrupted and decomposed resulting in grain refined near gamma microstructure. The α 2+γ lamellae structure near interdendritic regions decomposes almost completely into γ grains, but near dendrite cores incompletely into γ grains with a small amount of α 2 particles or needles around or in it. However, compared with the alloy with 1% (mole fraction) Mn, more α 2 phase is retained in the alloy with 2% (mole fraction) Mn. α 2 phase contains more Mn and is more stable in the alloy with 2% (mole fraction) Mn than in that with 1%(mole fraction) Mn. This makes its grain refinement more difficult. The amount of α 2 phase decreases following (1 250 ℃, 7 h-1 150 ℃, 15 h) for 3 cycles heat treatment. The microstructures of Ti47Al8NbxMn (mole fractions,%) alloy with x = 1 or 2 were studied on as-cast, as-HIPped and on heat-treated samples. The results showed that Mn element is β phase stabilizer and promotes the formation of β B 2 phase exists at the dendrite cores of the as-cast microstructures. This phase is metastable and can be completely decomposed into α and (or) γ during 1 200 ℃, 200 MPa, 4 h HIP process. In the as-HIPed alloy with 1% (mole fraction) Mn addition, the α 2 + γ lamellae structure is interrupted and decomposed resulting in grain refined near gamma microstructure. The α 2 + γ lamellae structure near interdendritic region decomposes almost completely into γ grains However, compared with the alloy with 1% (mole fraction) Mn, more α 2 phase is retained in the alloy with 2 % (mole fraction) Mn. α 2 phase contains more Mn and is mo Remaining in the alloy with 2% (mole fraction) Mn than in that with 1% (mole fraction) Mn. This makes its grain refinement more difficult. 150 ℃, 15 h) for 3 cycles heat treatment.
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